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새로운 헥사페닐을 포함한 청색 유기전기발광물질의 합성과 물성에 관한 연구
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.advisor | 계광열 | - |
| dc.contributor.author | 왕원판 | - |
| dc.date.accessioned | 2018-11-08T07:49:17Z | - |
| dc.date.available | 2018-11-08T07:49:17Z | - |
| dc.date.issued | 2006-02 | - |
| dc.identifier.other | 1143 | - |
| dc.identifier.uri | https://dspace.ajou.ac.kr/handle/2018.oak/7396 | - |
| dc.description | 학위논문(석사)--아주대학교 일반대학원 :분자과학기술학과,2006. 2 | - |
| dc.description.tableofcontents | I. Introduction------------------------------------------------------------------------------1 II. Results and Discussion---------------------------------------11 1. Synthesis of electroluminescent materials 1, 2 and 3-----------------11 1) Synthesis of 4'-(4-diphenylamino)styrylhexaphenylbenzene(1)-------------------------11 1-1) Synthetic scheme--------------------------------------------------------------------------11 1-2) Synthesis of 1-methyl-4-(phenylethynyl)benzene (8)-------------------------------12 1-3) Synthesis of 4'-methylhexaphenylbenzene (10) --------------------------------------13 1-4) Synthesis of 4'-bromomethylhexaphenylbenzene (11) ------------------------------14 1-5) Synthesis of (4'-diethylphosphomethyl)hexaphenylbenzene (12)---------------15 1-6) Synthesis of 4-(diphenylamino)benzaldehyde (14)---------------------------------16 1-7) Synthesis of 4'-(4-diphenylamino)styrylhexaphenylbenzene (1)-----------------16 2) Synthesis of 4'-(4-dimethylamino)styrylhexaphenylbenzene (2)--------------------17 2-1) Synthetic scheme--------------------------------------------------------------------------17 2-2) Synthesis of (hexaphenylbenzylmethyl)triphenylphosphonium bromide (15)-18 2-3) Synthesis of 4'-(4-dimethylamino)styrylhexaphenylbenzene (2)------- -----------19 3) Synthesis of 4'-(2-(9-ethyl-9H-carbazol-3-yl)-vinyl)hexaphenylbenzene (3)-------20 3-1) Synthetic scheme ------------------------------------------------------------------------20 3-2) Synthesis of 4'-(2-(9-ethyl-9H-carbazol-3-yl)-vinyl)hexaphenylbenzene (3)---- 21 2. Synthesis of electroluminescent materials 4 and 5--------------------22 1) Synthesis of 4',4''-(bis(4-diphenylamino)styryl)hexaphenylbenzene (4)------------22 1-1) Synthetic scheme -------------------------------------------------------------------------22 1-2) Synthesis of 1,2-dip-tolylethyne (19)-------------------------------------------------23 1-3) Synthesis of 4',4''-dimethylhexaphenylbenzene (20)-----------------------------24 1-4) 4',4''-Di(bromomethyl)hexaphenylbenzene (21)------------------------------------25 1-5) 4',4''-Bis(diethylphosphomethyl)hexaphenylbenzene (22)-------------------------26 1-6) Synthesis of 4',4''-(bis(4-diphenylamino)styryl)hexaphenylbenzene (4)----------26 2) Synthesis of 4',4’’-bis(2-(9-ethyl-9H-carbazol-3-yl)-vinyl)hexaphenylbenzene(5)27 2-1) Synthetic scheme--------------------------------------------------------------------------27 2-2) Synthesis of 4',4’’-bis(2-(9-ethyl-9H-carbazol-3-yl)-vinyl)hexaphenyl benzene (5)--------------------------------------------------------------------------------------28 3. Discussions on compounds 1, 2 and 3------------------------------------------30 3-1) Discussions on 1H-NMR spectra of compounds 1, 2 and 3-------------------------31 3-2) Discussions on UV/Vis and fluorescence spectra of compounds 1, 2 and 3------32 3-3) Discussions on cyclic voltammograms of compounds 1, 2 and 3---------36 3-4) Discussions on EL characteristics of compounds 1, 2 and 3----------------40 4. Discussions on compounds 4 and 5----------------------------------------------51 4-1) Discussions on 1H-NMR spectra of compounds 4 and 5----------------------------51 III. Experimental Section----------------------------------------------------------53 IV. References --------------------------------------------------------------------------63 V. Spectrum-------------------------------------------------------------------------------65 | - |
| dc.language.iso | eng | - |
| dc.publisher | The Graduate School, Ajou University | - |
| dc.rights | 아주대학교 논문은 저작권에 의해 보호받습니다. | - |
| dc.title | 새로운 헥사페닐을 포함한 청색 유기전기발광물질의 합성과 물성에 관한 연구 | - |
| dc.title.alternative | Yun-Fan Wang | - |
| dc.type | Thesis | - |
| dc.contributor.affiliation | 아주대학교 일반대학원 | - |
| dc.contributor.alternativeName | Yun-Fan Wang | - |
| dc.contributor.department | 일반대학원 분자과학기술학과 | - |
| dc.date.awarded | 2006. 2 | - |
| dc.description.degree | Master | - |
| dc.identifier.localId | 565027 | - |
| dc.identifier.url | http://dcoll.ajou.ac.kr:9080/dcollection/jsp/common/DcLoOrgPer.jsp?sItemId=000000001143 | - |
| dc.description.alternativeAbstract | Starting from 1-iodo-4-methylbenzene, hexaphenylbenzene-based organic compounds 1, 2, 3, 4 and 5 were synthesized as electroluminescent materials via a five-step synthetic route. The structures of those compounds were confirmed through 1H, 13C-NMR and FT-IR spectrums. The fluorescence spectra of the compounds 1, 2 and 3 showed a stable blue light-emitting behavior in the solution state. Cyclic voltammetry(CV) studies revealed that compounds 1, 2 and 3 had high electrochemical stabilities and the CV data also showed that the HOMO energy levels for the molecules are close to the work functions of anode materials such as ITO, indicating a favorable hole transport property of the molecules. Using compounds 1, 2 and 3, three types of EL devices were fabricated, which consisted of ITO/HTL/EML/ ETL/Al:Li, ITO/HTL/EML/HBL/ETL/Al:Li and ITO/HTL/ETL/Al:Li, respectively. The type I devices using compounds as an EML gave green electroluminescence, the type II devices using compounds as an EML showed that compounds 1 and 2 were not suitable for light emitting layer, and the type III devices using compounds as a HTL showed hole transport property. Comparing with NPD, type III EL devices using compounds 1 and 3 showed good hole transport property. The molecular structures of the compounds synthesized in this research are given as follows. | - |
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