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Stereoselective Total Syntheses of Musellarins D and E
- Author(s)
- 한재혁
- Alternative Author(s)
- Jae-hyuk Han
- Advisor
- 이동주
- Department
- 일반대학원 약학과
- Publisher
- The Graduate School, Ajou University
- Publication Year
- 2023-02
- Language
- eng
- Keyword
- Dehydrogenative Cycloetherification; Diastereoselectivity; Musellarins D and E; Natural Products; cis-2-Alkyl-6-aryl-3; 6-dihydro-2H-pyran
- Alternative Abstract
- The first and unified stereoselective total syntheses of naturally occurring (+)-musellarin D and musellarin E have been accomplished in 8 steps from the readily available α-tetralone, respectively. The key feature of our strategy includes highly diastereoselective dehydrogenative etherification and substrate-controlled benzylic allylation. The relative configuration of both musellarins D and E was revised.
- Fulltext
- Appears in Collections:
- Graduate School of Ajou University > Department of Pharmacy > 3. Theses(Master)
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