비극성 고분자 복합체를 위한 지방족 곁가지가 도입된 새로운 폴리아닐린 상용화제

Alternative Title
New Polyaniline Compatibilizers with Aliphatic Side Chains for Non-polar Polymer Composites
Author(s)
류종완
Advisor
권오필
Department
일반대학원 분자과학기술학과
Publisher
The Graduate School, Ajou University
Publication Year
2017-02
Language
eng
Keyword
고분자
Alternative Abstract
We investigate new polyaniline copolymers with flexible aliphatic side chains as a compatibilizer. Each polyaniline compatibilizers bearing small number of aliphatic side chain ; ethylhexyl (PA 2,6), hexyldecyl (PA 6,10), hexadecyl (PA 16) groups can increase the interfacial interaction between MWCNT and polyethylene (PE) matrix, also prevent dramatic reduction of its electrical conductivity. In absent of compatibilizer, the aggregation of MWCNT is observed in PE/MWCNT composite. The PA 6,10/MWCNT is well dispersed in PE matrix and excellent film forming ability. In contrast, PA 2,6/MWCNT and PA 16/MWCNT showed relatively poor dispersion in PE matrix which cause phase separation of composite film. As a result, PA6,10/MWCNT/PE exhibits lowest electrical resistance, which is significantly lower than PA 2,6/MWCNT/PE and PA16/MWCNT/PE.
URI
https://dspace.ajou.ac.kr/handle/2018.oak/11037
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Graduate School of Ajou University > Department of Molecular Science and Technology > 3. Theses(Master)
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