금속 산화물 나노입자의 이성분계 합성과 리튬이온 이차전지에서의 응용
DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | 김상욱 | - |
dc.contributor.author | 배형봉 | - |
dc.date.accessioned | 2018-11-08T08:02:23Z | - |
dc.date.available | 2018-11-08T08:02:23Z | - |
dc.date.issued | 2012-02 | - |
dc.identifier.other | 12173 | - |
dc.identifier.uri | https://dspace.ajou.ac.kr/handle/2018.oak/9698 | - |
dc.description | 학위논문(석사)아주대학교 일반대학원 :재료공학과,2012. 2 | - |
dc.language.iso | kor | - |
dc.publisher | The Graduate School, Ajou University | - |
dc.rights | 아주대학교 논문은 저작권에 의해 보호받습니다. | - |
dc.title | 금속 산화물 나노입자의 이성분계 합성과 리튬이온 이차전지에서의 응용 | - |
dc.title.alternative | Hyoung-Bong Bae | - |
dc.type | Thesis | - |
dc.contributor.affiliation | 아주대학교 일반대학원 | - |
dc.contributor.alternativeName | Hyoung-Bong Bae | - |
dc.contributor.department | 일반대학원 재료공학과 | - |
dc.date.awarded | 2012. 2 | - |
dc.description.degree | Master | - |
dc.identifier.localId | 570237 | - |
dc.identifier.url | http://dcoll.ajou.ac.kr:9080/dcollection/jsp/common/DcLoOrgPer.jsp?sItemId=000000012173 | - |
dc.subject.keyword | alloy nanoparticles | - |
dc.subject.keyword | anode materials | - |
dc.subject.keyword | battery | - |
dc.description.alternativeAbstract | In this study, we report the synthesis of MnxNi1-xO and MnyCo1-yO alloy nanoparticles by the thermal decomposition of the metal precursor in a surfactant. The synthesized particles were expected to have enhanced stability and their magnetic properties were expected to be different from those of particles synthesized in our previous experiment. We investigated the magnetic properties of the particles by using a superconducting quantum interference device (SQUID), after characterizing them by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), and other measurement techniques. Also, the synthesized nanoparticles were applied into anode materials in lithium ion batteries. The characteristic conversion reaction associated with Li uptake was observed and the anode performance became more improved according to an increase of Ni content. Especially, the higher Ni content (Mn0.33Ni0.66O) electrode exhibited a large reversible capacity (650 mAh g-1), a better initial efficiency (56%), an improved rate and cycle performance. From electrochemical impedance spectroscopy, the improved anode performance was ascribed to higher electrical/electrolyte conductivity or improved surface film property. | - |
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