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새로운5성분계 Mixed-metal Thiophosphate 계열 화합물의 합성•구조 및 특성
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.advisor | 윤호섭 | - |
| dc.contributor.author | 박소정 | - |
| dc.date.accessioned | 2018-11-08T07:51:47Z | - |
| dc.date.available | 2018-11-08T07:51:47Z | - |
| dc.date.issued | 2011-02 | - |
| dc.identifier.other | 11393 | - |
| dc.identifier.uri | https://dspace.ajou.ac.kr/handle/2018.oak/8232 | - |
| dc.description | 학위논문(석사)--아주대학교 일반대학원 :에너지시스템학부,2011. 2 | - |
| dc.description.tableofcontents | ABSTRACT ABSTRACT(Korean) Contents List of Figures List of Tables INTRODUCTION 12 CHAPTER I. The New Quinternary Mixed-metal Thiophosphates,Ay(TaxZr1-x)PS6 (A = K, Rb) 14 1.1 Abstract 15 1.2 Experimental 16 1.2.1 Synthesis 16 1.2.2 Crystallographic studies 17 1.2.3 UV/Vis spectroscopy 19 1.3 Result and Discussion 20 1.4 Figures 22 1.5 Tables 28 CHAPTER II. The New Quinternary Thiophosphates with Interlocked Structures A3Nb2Ti2P5S24 (A=Rb, Cs) 37 2.1.Abstract 38 2.2.Experimental 39 2.2.1 Synthesis 39 2.2.2 Crystallographic studies 39 2.2.3 UV/Vis spectroscopy 40 2.3 Result and Discussion 42 2.4 Figures 44 2.5 Tables 50 APPENDIX. The Quinternary Thiophosphate, Cs0.5Ag0.5Nb2PS10 60 3.1 INTRODUCTION 61 3.2 Abstract 62 3.3 Experimental 63 3.3.1 Synthesis 63 3.3.2 Crystallographic studies 63 3.4 Result and Discussion 65 3.5 Figures 67 3.6.Tables 69 REFERENCE 78 | - |
| dc.language.iso | eng | - |
| dc.publisher | The Graduate School, Ajou University | - |
| dc.rights | 아주대학교 논문은 저작권에 의해 보호받습니다. | - |
| dc.title | 새로운5성분계 Mixed-metal Thiophosphate 계열 화합물의 합성•구조 및 특성 | - |
| dc.title.alternative | Synthesis and Characterization of New Quinternary Mixed-metal Thiophosphates | - |
| dc.type | Thesis | - |
| dc.contributor.affiliation | 아주대학교 일반대학원 | - |
| dc.contributor.alternativeName | Sojeong Park | - |
| dc.contributor.department | 일반대학원 에너지시스템학부 | - |
| dc.date.awarded | 2011. 2 | - |
| dc.description.degree | Master | - |
| dc.identifier.localId | 569174 | - |
| dc.identifier.url | http://dcoll.ajou.ac.kr:9080/dcollection/jsp/common/DcLoOrgPer.jsp?sItemId=000000011393 | - |
| dc.subject.keyword | Thiophosphates | - |
| dc.subject.keyword | Chalcogenide | - |
| dc.description.alternativeAbstract | 2) A3Nb2Ti2P5S24 The new quinternary thoiphosphates, A3Nb2Ti2P5S24 (A = Rb, Cs) have been prepared with the use of halide fluxes and the crystal structure of the compound have been determined by single crystal X-ray diffraction methods. The compounds of A3Nb2Ti2P5S24 (A = Rb, Cs) have been synthesized and crystallize in space group C_2h^6-C2/c the monoclinic system with two formula units in a cell dimensions: a = 13.3326(4) Å, b = 27.3161 (7) Å, c = 11.7834 (4) Å, β = 116.1847 (9) °, V = 3851.1 (2) Å 3 for Rb3Nb2Ti2P5S24, a = 13.4219 (4) Å, b = 27.5078 (1) Å, c = 11.8079 (4) Å, β = 116.0479 (8) °, V = 3916.8 (2) Å3 for Cs3Nb2Ti2P5S24 The structure of the title compounds are composed of octahedral TiS6, tetrahedral PS4, and bicapped trigonal prismatic Nb2S12. The polyhedra form a three-dimensional framework by sharing S atoms. Two frameworks related by an inversion intertwined but there is no bonding interaction between them. The charge balance of the compound can be represented by the formula [A+]3[Nb4+]2[Ti4+]2[PS43-]5[S22-]2. | - |
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